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分子筛由于具有规则的孔道结构、适宜的酸性、良好的热和水热稳定性等特点,广泛应用于吸附、分离、离子交换及催化等领域。传统水热法制备分子筛因需要使用大量溶剂和有机模板剂,存在合成效率低、生产成本高、污染环境等一系列问题。近年来,随着"绿色化学"理念的深入人心,开发绿色、可持续的分子筛制备路线备受关注,逐渐成为该领域的研究热点。本文主要从水热法、离子热法、干胶法以及无溶剂法等几个方面,对国内外分子筛绿色合成的最新研究进展进行综述,并归纳比较上述合成方法的优缺点。最后,提出目前绿色合成分子筛过程中存在的问题,展望其未来发展前景。 相似文献
84.
Qiang Xia Tao Feng Xiaowei Lou Ying Wang Yangying Sun Daodong Pan Jinxuan Cao 《International Journal of Food Science & Technology》2020,55(2):669-680
As a decisive attribute, flavour could be influenced by HP treatments through multiple physical and chemical pathways within the high pressure (HP)-assisted meat curing process. This investigation aimed to identify the major pathway influencing volatile flavour patterns of two representative vinasse-cured duck (VCD) products with HP treatments (150–300 MPa/15 min), including wet and dry types, by employing headspace fingerprinting as an untargeted approach. Results suggested that HP treatments greatly lowered moisture contents and increased Warner-Bratzler shear force and thiobarbituric acid reactive substances of the cured samples. According to multivariate models, the volatile flavour patterns of the HP-processed VCD could be clearly separated from the unprocessed samples, but the VCD pressurised at different intensities represented similar volatile fingerprinting, which was validated by e-nose analysis. The discriminant analysis (OPLS-DA) model outlined vinasse-derived ethanol, acetic acid, 3-methyl-1-butanol, 2-methyl-1-butanol, phenethyl alcohol and 2-methyl-3-octanone as the major discriminant aromas across the unpressurised and pressurised samples. 相似文献
85.
Bo Zhong Jinze Zhang Hanqun Wang Long Xia Chunyu Wang Xiaodong Zhang Xiaoxiao Huang Guangwu Wen 《International Journal of Applied Ceramic Technology》2020,17(6):2598-2611
Novel SiC-based nanomaterials, namely the nitrogen and aluminum co-doped SiC@SiO2 core-shell nanowires and nitrogen-doped SiO2/Al2O3 nanoparticles, have been fabricated through a facile thermal treatment process based on the chemical vapor deposition and vapor-liquid reaction. These nanomaterials show remarkable hydrophobicity with a water contact angle (CA) over 140°, which are aroused by the surface zigzag morphology of the nanostructures and the hydrocarbyl groups generated during the preparation process. Moreover the nanocomposites also exhibit relatively prominent microwave absorption (MA) properties in the frequency range of 2.0-18.0 GHz. The minimum reflection loss (RL) value as low as −23.68 dB can be observed at 14.16 GHz when the absorber thickness is 2.6 mm with a loading rate of 16.7 wt%. And the nanocomposites-based absorbent can achieve an effective absorption bandwidth (RL < −10 dB) of 4.48 GHz with the absorbent thickness of 2.5 mm. This enhanced microwave attenuation performance can be attributed to multiple polarizations and perfect impedance matching conditions, as well as multiple internal reflections. These marvelous properties make these N and Al co-doped SiC@SiO2 core-shell nanowires and N-doped SiO2/Al2O3 nanoparticles display extensive application potential as MA materials in harsh environment. 相似文献
87.
热浸镀Al–Si合金涂层是一种有效的现代钢铁防腐涂层,但熔融Al–Si合金腐蚀已成为热浸镀Al–Si合金生产线沉没辊及其备件亟待解决的关键问题之一。本工作采用大气等离子喷涂技术制备Y2O3部分稳定ZrO2(YSZ)/NiCrAlY防护涂层,研究了喷涂功率对YSZ涂层组织和力学性能的影响和涂层在700℃下Al–Si熔体中的腐蚀行为。结果表明,YSZ涂层是由板条和层间柱状晶粒组成的典型层状结构,随着喷涂功率从37 kW增至46 kW,层间柱状结晶呈长大趋势;YSZ涂层主要由t-ZrO2相和少量m-ZrO2相组成,喷涂功率对涂层相组成无明显影响;喷涂功率为40 kW的YSZ涂层具有较高的显微硬度642.4 HV0.3和结合强度62 MPa。此外,当带有涂层的样品在700℃的Al–Si熔液中腐蚀240 h后,YSZ涂层与高温Al–Si熔液之间的界面没有反应层生成,同时Al–Si合金熔液中的Al和Si元素也未渗透进YSZ涂层内部,表明YSZ/NiCrAlY防护涂层有效地将Al–Si合金熔体阻挡在涂层表面。 相似文献
88.
Chao Lu Xiaoxue Liu Yufei Xia Qing Li Leping Dang Xinyi He Zhanzhong Wang 《化学工程与技术》2020,43(3):422-428
Measurement methods of metastable zone width (MZW) and nucleation induction time for melting layer crystallization of palm oil (PO) and its olein/stearin (POL/PST) were established, and the effects of cooling rate (corresponding to various supercoolings) on MZWs and induction time for melting layer crystallization of PO, POL, and PST were determined. The results indicated that the MZW coherently rose with increasing cooling rates with respect to PO and POL, while it declined with higher cooling rates for PST. The induction period results demonstrated that the nucleation induction periods of PO, PST, and POL decreased with increasing supercoolings, and the lag time for nucleation negatively correlated to the melting point of oils at the same supercooling. These data could offer significant instruction in designing and controlling the melting layer crystallization process for palm oil. 相似文献
89.
Jinwei Yin Peilong Zhou Hanqin Liang Dongxu Yao Yongfeng Xia Kaihui Zuo YuPing Zeng 《金属学报(英文版)》2020,33(12):1609-1617
Cu matrix composites reinforced by TiB2/TiN ceramic reinforcements (Cu/TBN composites) were prepared by hot pressing method. Prior to the hot pressing, Cu/TiB2/TiN composite powders (CTBN powders), which were used as the starting materials of Cu/TBN composites, were fabricated by self-propagating high-temperature synthesis method. The CTBN particles were found to be in a special core-shell structure with a Cu-Ti alloy core and a TiB2/TiN ceramic shell. The test results presented obvious improvements in mechanical properties. The highest ultimate tensile strength reached up to 297 MPa, 77 MPa higher than that of Cu. And the highest hardness reached up to 70.7 HRF, 15.7 HRF higher than that of Cu. A comparative study indicated that the core-shell structured particles could bring about more obvious strengthening effect than the traditional irregularly shaped particles, which was due to the improved Cu/ceramics interfacial bonding, the linkage strengthening effect of both TiB2 and TiN, and higher load bearing ability of the core-shell structured reinforcements. 相似文献
90.